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氢氧化钾的物化性质及其他安全事项
来源:http://www.jnjdbc.cn/ 日期:2023-04-25 发布人:admin
氢氧化钾白色斜方结晶,工业品为白色或淡灰色块状及棒状。相对密度2.044(20℃)。熔点360.4℃。沸点1320~1324℃。易溶于水,溶解时放出大量溶解热,有极强的吸水性,在空气中能吸收水分而溶解,并吸收二氧化碳逐渐变成碳酸钾。溶于乙醇,微溶于醚。有极强的碱性和腐蚀性,其性质与烧碱相似。下面精萘厂家为您讲解:
Potassium hydroxide is a white rhombic crystal, and industrial products are white or light gray block and rod shaped. Relative density 2.044 (20 ℃). Melting point 360.4 ℃. Boiling point 1320~1324 ℃. It is easily soluble in water and emits a large amount of heat when dissolved. It has strong water absorption ability and can absorb water to dissolve in the air, gradually transforming carbon dioxide into potassium carbonate. Soluble in ethanol, slightly soluble in ether. It has extremely strong alkalinity and corrosiveness, and its properties are similar to those of caustic soda. The refined naphthalene manufacturer will explain to you:
一、理化性质:
1、 Physical and chemical properties:
外观与性状:白色晶体,易潮解。
Appearance and properties: White crystals, easily deliquescent.
熔点(oC):360.4
Melting point (oC): 360.4
溶解性:溶于水、乙醇,微溶于醚.
Solubility: Soluble in water and ethanol, slightly soluble in ether
沸点(oC):1320
Boiling point (oC): 1320
相对密度(水=1):2.04
Relative density (water=1): 2.04
饱和蒸气压(kPa):0.13(719℃)
Saturated vapor pressure (kPa): 0.13 (719 ℃)
燃烧爆炸危险性
Risk of combustion and explosion
稳定性:稳定
Stability: Stable
燃烧分解产物:可能产生有害的毒性烟雾
Combustion decomposition products: May produce harmful toxic smoke
聚合危害:不聚合
Polymerization hazard: non polymerization
二、其他安全事项:
2、 Other safety precautions:
禁忌物:强酸、易燃或可燃物、二氧化碳、酸酐、酰基氯。
Taboos: Strong acids, flammable or combustible substances, carbon dioxide, anhydride, acyl chloride.
燃烧性:本品不燃,具强腐蚀性、强刺激性,可致人体灼伤。
Flammability: This product is non flammable, highly corrosive and irritating, and can cause burns to the human body.
危险特性:与酸发生中和反应并放热。本品不会燃烧,遇水和水蒸气大量放热,形成腐蚀性溶液。具有强腐蚀性。
Hazard characteristics: Neutralization reaction with acid and release of heat. This product does not burn and releases a large amount of heat when exposed to water and steam, forming a corrosive solution. Has strong corrosiveness.
消防措施:用水、砂土扑救,但须防止物品遇水产生飞溅,造成灼伤。
Fire protection measures: Use water and sand to extinguish the fire, but it is necessary to prevent items from splashing and causing burns when exposed to water.
毒性
toxicity
接触限值前苏联MAC(mg/m3):0.5;TLVWN:ACGIH2mg/m3
Exposure limit of former Soviet Union MAC (mg/m3): 0.5; TLVWN:ACGIH2mg/m3
急性毒性:LD50:273mg/kg(大鼠经口)LC50:无资料
Acute toxicity: LD50: 273mg/kg (rat oral) LC50: No data available
健康危害
Health hazards
本品具有强腐蚀性。粉尘刺激眼和呼吸道,腐蚀鼻中隔;皮肤和眼直接接触可引起灼伤;误服可造成消化道灼伤,粘膜糜烂、出血,休克。
This product has strong corrosiveness. Dust irritates eyes and respiratory tract, corrodes nasal septum; Direct contact between skin and eyes can cause burns; Misadministration can cause gastrointestinal burns, mucosal erosion, bleeding, and shock.
急救
first aid
皮肤接触:立即脱去污染的衣着,用大量流动清水冲洗至少15分钟。就医。眼睛接触:立即提起眼睑,用大量流动清水或生理盐水彻底冲洗至少15分钟。就医。
Skin contact: Immediately remove contaminated clothing and rinse with plenty of flowing water for at least 15 minutes. Seek medical attention. Eye contact: Immediately lift the eyelids and rinse thoroughly with a large amount of flowing water or physiological saline for at least 15 minutes. Seek medical attention.
吸入:迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难,给输氧。如呼吸停止,立即进行人工呼吸。就医。
Inhalation: Quickly remove from the scene to a place with fresh air. Maintain unobstructed respiratory tract. If breathing is difficult, administer oxygen. If breathing stops, immediately perform artificial respiration. Seek medical attention.
食入:用水漱口,给饮牛奶或蛋清。就医。
Ingestion: Rinse mouth with water and drink milk or egg white. Seek medical attention.
防护
protect
工程控制:密闭操作。提供安全淋浴和洗眼设备。
Engineering control: closed operation. Provide safety showers and eye wash equipment.
呼吸系统防护:可能接触其粉尘时,必须佩戴头罩型电动送风过滤式防尘呼吸器。必要时,佩戴空气呼吸器。身体防护:穿橡胶耐酸碱服。
Respiratory system protection: When there is a possibility of contact with its dust, it is necessary to wear a hood type electric air supply filter dust respirator. If necessary, wear an air respirator. Body protection: Wear rubber acid and alkali resistant clothing.
眼睛防护:呼吸系统防护中已作防护。
Eye protection: Protective measures have been taken in respiratory system protection.
手防护:戴橡胶耐酸碱手套。
Hand protection: Wear rubber acid and alkali resistant gloves.
其他防护:工作现场禁止吸烟、进食和饮水,饭前要洗手。工作完毕,淋浴更衣。注意个人清洁卫生。
Other protections: Smoking, eating, and drinking are prohibited at the workplace, and hands should be washed before meals. After work, take a shower and change clothes. Pay attention to personal cleanliness and hygiene.
泄漏处理
Leakage handling
隔离泄漏污染区,限制出入。建议应急处理人员戴防尘面具(全面罩),穿防酸碱工作服。不要直接接触泄漏物。小量泄漏:用洁净的铲子收集于干燥、洁净、有盖的容器中。也可以用大量水冲洗,洗水稀释后放入废水系统。大量泄漏:收集回收或运至废物处理场所处置
Isolate the contaminated area and restrict access. It is recommended that emergency personnel wear dust masks (full face masks) and acid and alkali resistant work clothes. Do not come into direct contact with leaks. Small leakage: Collect with a clean shovel in a dry, clean, and covered container. You can also rinse with a large amount of water, dilute the washing water and put it into the wastewater system. Large amount of leakage: collected for recycling or transported to waste disposal sites for disposal
储运
storage and transportation
储存于阴凉、干燥、通风良好的库房。远离火种、热源。库内湿度不大于85%。包装必须密封,切勿受潮。应与易(可)燃物、酸类等分开存放,切忌混储。储区应备有合适的材料收容泄漏物。
Store in a cool, dry, and well ventilated warehouse. Keep away from sparks and heat sources. The humidity inside the warehouse shall not exceed 85%. The packaging must be sealed and protected from moisture. It should be stored separately from flammable (combustible) substances, acids, etc., and mixed storage should be avoided. The storage area should be equipped with suitable materials to contain leaks.
运输:铁路运输时,钢桶包装的可用敞车运输。起运时包装要完整,装载应稳妥。运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与易燃物或可燃物、酸类、食用化学品等混装混运。运输时运输车辆应配备泄漏应急处理设备。更多相关的内容就来我们网站http://www.jnjdbc.cn咨询吧!
Transportation: During railway transportation, steel drum packaging can be transported by gondola cars. The packaging should be complete during shipment and the loading should be secure. During transportation, it is necessary to ensure that the container does not leak, collapse, fall, or be damaged. It is strictly prohibited to mix and transport flammable or combustible materials, acids, edible chemicals, etc. Transport vehicles should be equipped with leakage emergency response equipment during transportation. For more relevant content, come to our website http://www.jnjdbc.cn Consult!
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[2018-08-23]
精萘对人体有多种危害,主要包括: Naphthalene poses various hazards to the human body, including: 急性中毒...